Encapsulation of Keggin-type anions in reduced molybdenum–iron-type Keplerates as a general phenomenon
| Autor: | Thorsten Glaser, Ana Maria Todea, Lise-Marie Chamoreau, Pierre Gouzerh, René Thouvenot, Stephan Walleck, Ahmed Jasim M. Al-Karawi, Achim Müller |
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| Rok vydání: | 2012 |
| Předmět: |
Aqueous solution
Sodium molybdate Potassium Keplerate Inorganic chemistry chemistry.chemical_element Keggin ions Chloride Magnetic susceptibility Inorganic Chemistry chemistry.chemical_compound chemistry Core-shell clusters Molybdenum Materials Chemistry medicine Physical and Theoretical Chemistry Host–guest chemistry Host-guest chemistry Dissolution medicine.drug |
| Zdroj: | Inorganica Chimica Acta. 389:107-111 |
| ISSN: | 0020-1693 |
| DOI: | 10.1016/j.ica.2012.01.062 |
| Popis: | Upon standing in air at room temperature, acidified aqueous solutions (pH 2) obtained by dissolving sodium molybdate, iron(II) chloride, acetic acid and potassium dodecatungstoborate led to the formation of greenish thin plate crystals (1) containing discrete clusters. Upon drying 1 at room temperature cross-linking of the clusters occurs in a solid-state reaction which leads to compound 2. Based on crystallographic studies of 1 and on extensive physical characterization (vibrational, NMR, Mossbauer spectra and magnetic susceptibility measurements) of 2, it was shown that compounds 1 and 2 contain reduced spherical {Mo72Fe30} Keplerate-type shells encapsulating non-reduced tungstoborate Keggin-type anions. The properties and structures of these compounds are compared to related hybrid structures containing in principle easier reducible molybdophosphate or molybdosilicate cores. According to the results the present type of encapsulation can be considered as a general phenomenon. (C) 2012 Elsevier B.V. All rights reserved. |
| Databáze: | OpenAIRE |
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