Generation of Strong Basicity in Metal-Organic Frameworks: How Do Coordination Solvents Matter?

Autor: Song-Song Peng, Guo-Song Zhang, Xiang-Bin Shao, Chen Gu, Xiao-Qin Liu, Lin-Bing Sun
Rok vydání: 2022
Předmět:
Zdroj: ACS applied materialsinterfaces. 14(6)
ISSN: 1944-8252
Popis: Solid strong bases with an ordered pore structure (OPS-SSBs) have attracted much attention because of their high catalytic activity and shape selectivity as heterogeneous catalysts in various reactions. Nevertheless, high temperatures are required to fabricate OPS-SSBs by using traditional methods. Herein, we report for the first time that the coordination solvents affect basicity generation in metal-organic frameworks (MOFs) greatly and that strong basicity can be formed at comparatively low temperatures. A typical MOF, MIL-53, was employed, and three different solvents, namely, water, methanol, and
Databáze: OpenAIRE