| Autor: |
Chongchao Zhao, Ken I. Hardcastle, Choon Sung Kambara, Djamaladdin G. Musaev, Craig L. Hill, Tianquan Lian, Zhuangqun Huang, William Rodríguez-Córdoba, Kevin P. O’Halloran |
| Rok vydání: |
2011 |
| Předmět: |
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| Zdroj: |
Journal of the American Chemical Society. 133(50) |
| ISSN: |
1520-5126 |
| Popis: |
[P(4)W(35)O(124){Re(CO)(3)}(2)](16-) (1), a Wells-Dawson [α(2)-P(2)W(17)O(61)](10-) polyoxometalate (POM)-supported [Re(CO)(3)](+) complex containing covalent W(VI)-O-Re(I) bonds has been synthesized and characterized by several methods, including X-ray crystallography. This complex shows a high visible absorptivity (e(470 nm) = 4000 M(-1) cm(-1) in water) due to the formation of a Re(I)-to-POM charge transfer (MPCT) band. The complex was investigated by computational modeling and transient absorption measurements in the visible and mid-IR regions. Optical excitation of the MPCT transition results in instantaneous ( |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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