Coarsening behaviour and interfacial structure of γ′ precipitates in Co-Al-W based superalloys
| Autor: | Jonathan S. Barnard, Paul A. Midgley, V.A. Vorontsov, K.M. Rahman, H.-Y. Yan, David Dye |
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| Přispěvatelé: | Engineering & Physical Science Research Council (EPSRC), Rolls-Royce Plc, Engineering & Physical Science Research Council (E |
| Rok vydání: | 2016 |
| Předmět: |
Ostwald ripening
Materials science Polymers and Plastics Tantalum chemistry.chemical_element Thermodynamics 02 engineering and technology Tungsten TS 01 natural sciences symbols.namesake Aluminium 0103 physical sciences Solvus 0912 Materials Engineering High-resolution transmission electron microscopy Materials 010302 applied physics Metals and Alloys 021001 nanoscience & nanotechnology Electronic Optical and Magnetic Materials Superalloy Nickel Crystallography chemistry Ceramics and Composites symbols 0210 nano-technology 0913 Mechanical Engineering |
| Zdroj: | Acta Materialia. 120:14-23 |
| ISSN: | 1359-6454 |
| DOI: | 10.1016/j.actamat.2016.08.023 |
| Popis: | This work discusses the effects of alloying on the coarsening behaviour of the L12 ordered γ′ phase and the structure of the γ/γ′ interfaces in three Co-Al-W base superalloys aged at ∼90 °C below the respective solvus temperatures: Co-7Al-7W, Co-10Al-5W-2Ta and Co-7Al-7W-20Ni (at.%). The coarsening kinetics are adequately characterised by the classical Lifshitz-Slyozov-Wagner model for Ostwald ripening. Co-7Al-7W exhibited much slower coarsening than its quaternary derivatives. Alloying can be exploited to modify the coarsening kinetics either by increasing the solvus temperature by adding tantalum, or by adding nickel to shift the rate controlling mechanism towards dependence on the diffusion of aluminium rather than tungsten. Lattice resolution STEM imaging was used to measure the widths of the order-disorder (structural) and Z-contrast (compositional) gradients across the γ/γ′ interfaces. Similarly to nickel base superalloys, the compositional gradient was found to be wider than the structural. Co-7Al-7W-20Ni had much wider interface gradients than Co-7Al-7W and Co-10Al-5W-2Ta, which suggests that its γ′ phase stoichiometry is less constrained. A possible correlation between temperature and misfit normalised r vs. t1/3 coarsening rate coefficients and the structural gradient width has also been identified, whereby alloys with wider interfaces exhibit faster coarsening rates. |
| Databáze: | OpenAIRE |
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