Henry's law constants for polychlorinated biphenyls: experimental determination and structure-property relationships

Autor:	Eduard Hornung, Rainer Brueggemann, Joachim Altschuh, Helmut Santl, Egmont Wolff, Otto G. Piringer, Siegfried Brunner
Přispěvatelé:	Publica
Rok vydání:	1990
Předmět:	determination Chemistry structure-property relationship Environmental Chemistry Structure property Organic chemistry Thermodynamics Henry's law constants General Chemistry partition coefficient Dynamic method polychlorinated biphenyl Henry's law
Zdroj:	Environmental Science & Technology. 24:1751-1754
ISSN:	1520-5851 0013-936X
Popis:	Methods to experimentally determine Henry's law constants (HLCs) can be roughly divided into two parts: kinetic and static thermodynamic methods. Here a dynamic method is presented, which combines the advantages and avoids the inherent difficulties of these two methods. A technical mixture of polychlorinated biphenyls (PCBs) was analyzed and 58 PCB congeners have been reliably identified. In addition, 11 PCB congeners were found, which are less reliably identified. The measurements have shown that a sytematic dependence on the chlorine number and substitution pattern can be estabilished. This set of HLCs allows formulation of some estimation equations.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7134b06da50ead8f24f05bdf0f41958e https://doi.org/10.1021/es00081a021 Zobrazit plný text záznamu