Cooperative self-assembly and gelation of organogold(i ) complexes via hydrogen bonding and aurophilic Au⋯Au interactions
| Autor: | Feng Wang, Chengming Wang, Zhongxin Zhang, Zongchun Gao, Jiangjun Chen, Zhao Gao |
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| Rok vydání: | 2017 |
| Předmět: |
genetic structures
010405 organic chemistry Chemistry Hydrogen bond Intermolecular force Metals and Alloys Supramolecular chemistry General Chemistry Synergistic combination 010402 general chemistry Photochemistry 01 natural sciences Catalysis 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound Crystallography Monomer Materials Chemistry Ceramics and Composites Self-assembly |
| Zdroj: | Chem. Commun.. 53:11552-11555 |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/c7cc05613c |
| Popis: | With the synergistic combination of intermolecular Au(i)-Au(i) and hydrogen bonding interactions, a rod-coil alkynyl-gold(i)-isocyanide monomer tends to form supramolecular fibers and gels via a cooperative nucleation-elongation self-assembly mechanism, which display Ag(i) ion-triggered responsiveness. |
| Databáze: | OpenAIRE |
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