1,1,1-Tris(hydroxymethyl)ethane as a New, Efficient, and Versatile Tripod Ligand for Copper-Catalyzed Cross-Coupling Reactions of Aryl Iodides with Amides, Thiols, and Phenols
Autor: | Yao-Jung Chen, Hsin-Hung Chen |
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Rok vydání: | 2006 |
Předmět: |
Tris
Ligands Biochemistry Catalysis Coupling reaction chemistry.chemical_compound Phenols Alkanes Organic chemistry Hydroxymethyl Sulfhydryl Compounds Physical and Theoretical Chemistry Amination Ligand Aryl Organic Chemistry Tripod (photography) General Medicine Iodides Amides Combinatorial chemistry chemistry Copper catalyzed Indicators and Reagents Copper |
Zdroj: | Organic Letters. 8:5609-5612 |
ISSN: | 1523-7052 1523-7060 |
Popis: | 1,1,1-tris(hydroxymethyl)ethane was presented as a new, efficient, and versatile tridentate O-donor ligand suitable for the copper-catalyzed formation of C-N, C-S, and C-O bonds. This inexpensive and commercially available tripod ligand has been demonstrated to facilitate the copper-catalyzed cross-coupling reactions of aryl iodides with amides, thiols, and phenols to afford the corresponding desired products in good to excellent yields. [reaction: see text]. |
Databáze: | OpenAIRE |
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