Preparation and Crystallographic Characterization of C60{η1-Ru(CO)2(η5-C5H5)}2: A Locally Crowded Organometallic Fullerene Without the Usual η2-Bonding

Autor:	Alan L. Balch, Faye L. Bowles, Marilyn M. Olmstead
Rok vydání:	2014
Předmět:	Diffraction Crystallography chemistry.chemical_compound Colloid and Surface Chemistry Fullerene Chemistry General Chemistry Biochemistry Single crystal Toluene Catalysis Characterization (materials science)
Zdroj:	Journal of the American Chemical Society. 136:3338-3341
ISSN:	1520-5126 0002-7863
DOI:	10.1021/ja4120677
Popis:	The reaction of {(η(5)-C5H5)Ru(CO)2}2 with C60 in toluene solution under thermal or photolytic conditions produces C60{η(1)-Ru(CO)2(η(5)-C5H5)}2, whose structure has been determined by single crystal X-ray diffraction. The two Ru(CO)2(η(5)-C5H5) units are bound at the opposite ends of a hexagon on the fullerene surface and are closely intertwined.
Databáze:	OpenAIRE
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