Comment on: 'Synthesis of dodecamolybdoantimonate(v ) salts containing the Keggin structure' by Raj P. Singh, Radheshyam P. Khatri, Jean Dubois, Sushma S. Gaur and Mitsuo Abe, J. Chem. Soc., Dalton Trans., 1990, 947–951
| Autor: | Hans Hartl, Hans-Joachim Lunk |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
Hexagonal crystal system
Potassium Molybdenum oxide chemistry.chemical_element 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Medicinal chemistry 0104 chemical sciences Rubidium Inorganic Chemistry chemistry.chemical_compound Keggin structure chemistry Caesium Ammonium 0210 nano-technology |
| Zdroj: | Dalton Transactions. 47:15613-15615 |
| ISSN: | 1477-9234 1477-9226 |
| DOI: | 10.1039/c8dt00712h |
| Popis: | The existence of a dodecamolybdoantimonate(v) anion with the Keggin structure would be a highlight of the heteropolyoxometalate chemistry as a whole. However, we could not confirm the existence of ammonium, potassium, rubidium and cesium dodecamolybdoantimonate as claimed by the authors. As a matter of fact, the authors misinterpreted their presented experimental data. Instead of the dodecamolybdoantimonates, the well-known hexagonal molybdenum oxide was prepared. The given misinformation has to be corrected, even 28 years after its publication. |
| Databáze: | OpenAIRE |
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