Strong Coordination of Tetraphenylborate Anion to Copper(I) Bipyridine and Phenanthroline-Based Complexes and Its Effect on Catalytic Activity in the Cyclopropanation of Styrene

Autor:	Jeffrey D. Evanseck, Lauren M. Matosziuk, Tomislav Pintauer, Carolynne Ricardo
Rok vydání:	2008
Předmět:	chemistry.chemical_classification Tetraphenylborate Denticity Cyclopropanation Phenanthroline chemistry.chemical_element Photochemistry Copper Inorganic Chemistry chemistry.chemical_compound Bipyridine chemistry Transition metal Polymer chemistry Physical and Theoretical Chemistry Counterion
Zdroj:	Inorganic Chemistry. 48:16-18
ISSN:	1520-510X 0020-1669
DOI:	10.1021/ic801783r
Popis:	The synthesis, characterization, and cyclopropanation activity of tetrahedral copper(I) complexes with bipyridine- and phenanthroline-based ligands containing strongly coordinated tetraphenylborate anions are reported. Cu(I)(bpy)(BPh(4)), Cu(I)(phen)(BPh(4)), and Cu(I)(3,4,7,8-Me(4)phen)(BPh(4)) complexes are the first examples in which the BPh(4)(-) counterion chelates a transition metal center in bidentate fashion through eta(2) pi interactions with two of its phenyl rings.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::70f1dcf94ed3bb9a6ec0f67b7a47fc9d https://doi.org/10.1021/ic801783r Zobrazit plný text záznamu