Coordination, reactivity, and structural properties of electron-rich ethoxy- and dimethylamino-substituted 1,3-diketiminate ligands and their complexes
| Autor: | Dragoslav Vidovic, Michael A. Land, Peter T. K. Lee, Kai E. O. Ylijoki, Jetsuda Areephong, Bright Huo, Jason A. C. Clyburne, Katherine N. Robertson |
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| Rok vydání: | 2018 |
| Předmět: |
010405 organic chemistry
NacNac chemistry.chemical_element Crystal structure Zinc 010402 general chemistry 01 natural sciences Medicinal chemistry 3. Good health 0104 chemical sciences Rhodium Inorganic Chemistry chemistry.chemical_compound chemistry X-ray crystallography Alkoxy group Chelation Reactivity (chemistry) |
| Zdroj: | Dalton transactions (Cambridge, England : 2003). 47(30) |
| ISSN: | 1477-9234 |
| Popis: | In this paper we describe the synthesis, characterization, and X-ray crystal structures of two ligands, diethyl-N,N'-bis(p-tolyl)malonimidate and 1,3-bis(dimethylamino)-N,N'-bis(p-tolyl)propanediimidate. Their corresponding rhodium(i) dicarbonyl, dimethylaluminium, and bis-ligated zinc complexes have also been prepared and characterized. The donor properties of the ligands have been studied and have been compared to those of the traditional anionic N,N'-chelating ligand nacnac. |
| Databáze: | OpenAIRE |
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