Modelling approach for planar self-breathing PEMFC and comparison with experimental results
| Autor: | Andreas Schmitz, Christopher Hebling, Christoph Ziegler, Ed Fontes, Jürgen Schumacher, Marco Tranitz |
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| Přispěvatelé: | Publica |
| Jazyk: | angličtina |
| Rok vydání: | 2004 |
| Předmět: |
Hydrogen
Renewable Energy Sustainability and the Environment Condensation Self-breathing Analytical chemistry Limiting current Energy Engineering and Power Technology Proton exchange membrane fuel cell chemistry.chemical_element Mechanics Fick's laws of diffusion Modelling Cathode law.invention chemistry law Gaseous diffusion PEMfc Diffusion (business) Fuel cells 621.3: Elektrotechnik und Elektronik |
| Popis: | This paper presents a model-based analysis of a proton exchange membrane fuel cell (PEMFC) with a planar design as the power supply for portable applications. The cell is operated with hydrogen and consists of an open cathode side allowing for passive, self-breathing, operation. This planar fuel cell is fabricated using printed circuit board (PCB) technology. Long-term stability of this type of fuel cell has been demonstrated. A stationary, two-dimensional, isothermal, mathematical model of the planar fuel cell is developed. Fickian diffusion of the gaseous components (O2, H2, H2O) in the gas diffusion layers and the catalyst layers is accounted for. The transport of water is considered in the gaseous phase only. The electrochemical reactions are described by the Tafel equation. The potential and current balance equations are solved separately for protons and electrons. The resulting system of partial differential equations is solved by a finite element method using FEMLAB (COMSOL Inc.) software. Three different cathode opening ratios are realized and the corresponding polarization curves are measured. The measurements are compared to numerical simulation results. The model reproduces the shape of the measured polarization curves and comparable limiting current density values, due to mass transport limitation, are obtained. The simulated distribution of gaseous water shows that an increase of the water concentration under the rib occurs. It is concluded that liquid water may condense under the rib leading to a reduction of the open pore space accessible for gas transport. Thus, a broad rib not only hinders the oxygen supply itself, but may also cause additional mass transport problems due to the condensation of water. |
| Databáze: | OpenAIRE |
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