[7]-Helicene: a chiral molecular tweezer for silver(I) salts

Autor:	Benjamin Wardzinski, Dilraj K. Judge, Julia Schaefer, Marko Weimar, Ingo Krossing, Matthew J. Fuchter
Rok vydání:	2012
Předmět:	inorganic chemicals chemistry.chemical_classification Physics::Biological Physics Quantitative Biology::Biomolecules Inorganic chemistry Physics::Optics Ion Condensed Matter::Soft Condensed Matter Inorganic Chemistry chemistry.chemical_compound chemistry Helicene Computational chemistry Counterion
Zdroj:	Dalton transactions (Cambridge, England : 2003). 41(27)
ISSN:	1477-9234
Popis:	We have unambiguously demonstrated the binding of the silver(I) ion in the central cavity of [7]-helicene, given that the counterion is weakly coordinating. In such a binding mode, the helicene is functioning as a chiral molecular tweezer.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::705a76952288fefa15973579d1f917b0 https://pubmed.ncbi.nlm.nih.gov/22669116 Zobrazit plný text záznamu