The stability of singly and multiply charged La@C80 and La@C82 ions determined from kinetic energy release measurements
| Autor: | S. Feil, Paul Scheier, Olof Echt, K. Gluch, Tilmann D. Märk, S. Matt-Leubner, Chava Lifshitz, Baopeng Cao, Takatsugu Wakahara, Takeshi Akasaka |
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| Rok vydání: | 2006 |
| Předmět: |
Fullerene
Heat bath Chemistry Electronvolt chemistry.chemical_element Condensed Matter Physics Kinetic energy Dissociation (chemistry) Ion Physics::Atomic and Molecular Clusters Endohedral fullerene Lanthanum Physics::Chemical Physics Physical and Theoretical Chemistry Atomic physics Instrumentation Spectroscopy |
| Zdroj: | ResearcherID |
| ISSN: | 1387-3806 |
| DOI: | 10.1016/j.ijms.2005.11.022 |
| Popis: | We have measured the kinetic energy release distributions for unimolecular C 2 loss from singly and multiply charged endohedral La@C 80 z + and La@C 80 z + ions for charge states z = 1–3. Using finite heat bath theory, we deduce the dissociation energies for loss of C 2 . The charge state z has no statistically significant effect on the dissociation energies. The dissociation energies of endohedral fullerene ions are larger than those of the corresponding empty fullerene ions by a few tenths of an electron volt, but the differences are barely statistically significant. The small differences also imply that the complexation energies of La@C n z + and La@C n − 2 z + are identical within the experimental errors, for n = 80 and 82 and all charge states. |
| Databáze: | OpenAIRE |
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