Donor ligands based on tricoordinate boron formed by B–H-activation of bis(phosphine)boronium salts
| Autor: | Maik Grätz, Robert Langer, Leon Maser, Lisa Vondung, Arian Reincke, Andreas Bäcker |
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| Rok vydání: | 2017 |
| Předmět: |
inorganic chemicals
010405 organic chemistry Ligand Metals and Alloys chemistry.chemical_element General Chemistry 010402 general chemistry 01 natural sciences Catalysis 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound chemistry Polymer chemistry Materials Chemistry Ceramics and Composites Organic chemistry Boron Phosphine Palladium |
| Zdroj: | Chemical Communications. 53:7230-7233 |
| ISSN: | 1364-548X 1359-7345 |
| Popis: | We report a novel method for the preparation of PBP-pincer complexes from bis(phosphine)boronium salts. The central (R3P)2HB-moiety in a palladium complex is demonstrated to be a L-type ligand, therewith completing a series of pincer-type complexes with Z-, X- and L-type boron-based ligands, respectively. |
| Databáze: | OpenAIRE |
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