Competitive Interactions Within Cm(III) Solvation in Binary Water/Methanol Solutions

Autor:	Aurora E. Clark, Ping Yang, Morgan P. Kelley, Sue B. Clark
Rok vydání:	2018
Předmět:	Inorganic Chemistry 010304 chemical physics Chemistry 0103 physical sciences Solvation Binary number Thermodynamics Water methanol Electrolyte Physical and Theoretical Chemistry 010402 general chemistry 01 natural sciences 0104 chemical sciences
Zdroj:	Inorganic Chemistry. 57:10050-10058
ISSN:	1520-510X 0020-1669
DOI:	10.1021/acs.inorgchem.8b01214
Popis:	Competitive forces exist in multicomponent solutions, and within electrolytes they consist of both ion-solvent and solvent-solvent interactions. These can influence a myriad of processes, including ligand complexation. In the case of water/alcohol solutions, recent work revealed an interesting dilemma regarding the overall solution dynamics and organization as compared to solute-solvent interactions. This is particularly true for highly charged ions in solution, whose ion-solvent interactions were demonstrated to be highly sensitive to the composition of the immediate solvation environment. Faster solvent exchange should be observed about the ion, considering that second-order Møller-Plesset perturbation theory predicts an average decrease in ion-solvent dissociation energy when methanol enters the first solvation shell of Cm
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6fc919a4698221de9977125f5d2426b4 https://doi.org/10.1021/acs.inorgchem.8b01214 Zobrazit plný text záznamu