Stereoselective synthesis of N-alkylaziridines from N-chloroamines
| Autor: | Nicholas J. Palmer, Martin A. Wilson, Sean P. Bew, Vladimir Savic, Katy M. Soapi, David L. Hughes |
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| Rok vydání: | 2006 |
| Předmět: |
Molecular Structure
Chemistry Aziridines Chloramines Metals and Alloys Stereoisomerism General Medicine General Chemistry Aziridine Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound Cyclization Yield (chemistry) Materials Chemistry Ceramics and Composites Solvents Organic chemistry Stereoselectivity |
| Zdroj: | Chemical communications (Cambridge, England). (41) |
| ISSN: | 1359-7345 |
| Popis: | We report the first racemic and stereoselective synthesis of cis- and trans-N-alkylaziridines viaN-chloroamines; using this methodology an N-3,4,5-trimethoxybenzylaziridine was synthesised and efficiently cleaved, affording the corresponding NH aziridine in high yield. |
| Databáze: | OpenAIRE |
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