Tethered sensitizer-catalyst noble-metal-free molecular devices for solar-driven hydrogen generation
| Autor: | Zhong-Hua Zhong-Hua Pan, Jinqing Lin, Geng-Geng Luo, Di Sun |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
Materials science
010405 organic chemistry Nanotechnology Molecular systems engineering.material 010402 general chemistry 01 natural sciences 0104 chemical sciences Catalysis Inorganic Chemistry Electron transfer Intramolecular force Photocatalysis engineering Molecule Noble metal Hydrogen production |
| Zdroj: | Dalton transactions (Cambridge, England : 2003). 47(44) |
| ISSN: | 1477-9234 |
| Popis: | Inspired by natural photosynthesis in an organized assembly, compact H2-evolving molecular devices, which tether sensitizer and catalyst modules in one single molecule, present an opportunity to overcome the diffusion limit required for multi-component molecular systems, and increase intramolecular electron transfer rates from the photoactivated unit to the catalytic center to improve H2-evolving efficiency. Thereinto absolutely noble-metal free H2-evolving molecular devices are of particular interest because they don't contain precious and scarce noble-metal based components. This Frontier article focuses specifically on the recent advances in the design, synthesis, and photocatalytic properties of all-abundant-element molecular devices for photoinduced H2 generation via intramolecular processes. Some challenges and suggestions for future directions in this field are also illustrated. |
| Databáze: | OpenAIRE |
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