Ring-Opening Polymerization of ε-Caprolactone by Using Aluminum Complexes Bearing Aryl Thioether Phenolates: Labile Thioether Chelation

Autor:	Someswara Rao Kosuru, Yu-Lun Chang, Po-Yu Chen, Wei Lee, Yi-Chun Lai, Shangwu Ding, Hsuan-Ying Chen, Hsing-Yin Chen, Yung-Chi Chang
Rok vydání:	2022
Předmět:	Inorganic Chemistry Physical and Theoretical Chemistry
Zdroj:	Inorganic Chemistry. 61:3997-4008
ISSN:	1520-510X 0020-1669
Popis:	In this study, aluminum complexes bearing ferrocene-based and arylthiomethylphenolate ligands were synthesized, and their catalytic activity for ε-caprolactone (CL) polymerization was investigated. The catalytic activity of the reduced form of Al complexes was higher than that of the oxidized form. The CL polymerization rate of the reduced form
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6f9401d76861f95c70f944ed5fe17bf1 https://doi.org/10.1021/acs.inorgchem.1c03683 Zobrazit plný text záznamu