Tris(hydroxypropyl)phosphine Oxide: A Chiral Three-Dimensional Material with Nonlinear Optical Properties

Autor:	Jian Liu, Harry B. Gray, Christopher D. Incarvito, Nilay Hazari, Alec C. Durrell, Elsa C. Y. Yan
Rok vydání:	2010
Předmět:	Phosphine oxide Chemistry Hydrogen bond Inorganic chemistry Space group General Chemistry Crystal structure Condensed Matter Physics symbols.namesake Crystallography chemistry.chemical_compound symbols Moiety Molecule General Materials Science Raman spectroscopy Phosphine
Zdroj:	Crystal Growth & Design. 10:1482-1485
ISSN:	1528-7505 1528-7483
Popis:	The achiral C_(3v) organic phosphine tris(hydroxypropyl)phosphine oxide (1) crystallizes in the unusual chiral hexagonal space group P6_3. The structure is highly ordered because each phosphine oxide moiety forms three hydrogen bonds with adjacent hydroxy groups from three different molecules. The properties of the crystals and the presence of hydrogen bonding interactions were investigated using single crystal Raman spectroscopy. The crystals show nonlinear optical properties and are capable of efficient second harmonic generation.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6f8ffe1126a0a3d58df80d897353b9d4 https://doi.org/10.1021/cg1001286 Zobrazit plný text záznamu