A greener procedure for the synthesis of [Bu4N]2-cis-[Ru(4-carboxy-4′-carboxylate-2,2′-bipyridine)2(NCS)2] (N719), a benchmark dye for DSSC applications
| Autor: | G. Gorni, Paolo Righi, Valerio Borzatta, S. Muzzioli, S. Vierucci, Isabella Zama |
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| Přispěvatelé: | Vierucci, S., Muzzioli, S., Righi, P., Borzatta, V., Gorni, G., Zama, I. |
| Rok vydání: | 2016 |
| Předmět: |
Chemistry
General Chemical Engineering Chemistry (all) Nanotechnology 02 engineering and technology General Chemistry E factor 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Combinatorial chemistry 2 2'-Bipyridine 0104 chemical sciences Dye-sensitized solar cell chemistry.chemical_compound Chemical Engineering (all) Carboxylate 0210 nano-technology |
| Zdroj: | RSC Advances. 6:55768-55777 |
| ISSN: | 2046-2069 |
| DOI: | 10.1039/c6ra13550a |
| Popis: | A previously reported protocol for the synthesis of the commercial dye [Bu4N]2[Ru(4-carboxy-4′-carboxylate-2,2′-bipyridine)2(NCS)2] (N719) was thoroughly optimized in terms of the amount of input materials needed, reaction times and temperatures achieving significant reductions in all the three synthetic steps. This optimization allowed a 81% reduction of the Sheldon's E factor of the overall process. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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