Probing the electronic boundaries between trigonal and tetrahedral coordination at beryllium

Autor:	Matthias Müller, Magnus R. Buchner, Nils Spang
Rok vydání:	2020
Předmět:	education.field_of_study Materials science Population Infrared spectroscopy Halide chemistry.chemical_element Inorganic Chemistry Metal Crystallography Partial charge chemistry visual_art visual_art.visual_art_medium Reactivity (chemistry) Beryllium education Coordination geometry
Zdroj:	Dalton Transactions. 49:7708-7712
ISSN:	1477-9234 1477-9226
DOI:	10.1039/d0dt01442g
Popis:	NEt3 adducts to BeCl2, BeBr2 and BeI2 were synthesized and characterised via NMR and IR spectroscopy as well as X-ray diffractometry. Depending on the halide and the state of matter these are either mono- or dinuclear. Population analyses were performed to determine the influence of the metal's partial charge on the coordination geometry. Additionally, the reactivity of these compounds towards C–Cl- and O–H-bonds was studied.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6ee9cb5c026731dfe793121165223a6d https://doi.org/10.1039/d0dt01442g Zobrazit plný text záznamu