Key-and-lock commodity self-healing copolymers
Autor: | Marek W. Urban, Dmitriy Davydovich, Tugba Demir, Leah B. Casabianca, Ying Yang, Yunzhi Zhang |
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Rok vydání: | 2018 |
Předmět: |
Acrylate
Multidisciplinary Materials science Supramolecular chemistry 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences chemistry.chemical_compound symbols.namesake chemistry Chemical physics Covalent bond Self-healing symbols Copolymer van der Waals force Methyl methacrylate 0210 nano-technology |
Zdroj: | Science. 362:220-225 |
ISSN: | 1095-9203 0036-8075 |
DOI: | 10.1126/science.aat2975 |
Popis: | Simple routes to self-healing Biology provides many routes for self-healing or repair, but this trait is hard to endow into engineering materials. Although self-repair has been demonstrated for some polymers, it usually required specialized monomers. Urban et al. demonstrate that for a very narrow range of compositions, simple vinyl polymers based on methyl methacrylate and n -butyl acrylate show repeatable self-healing properties (see the Perspective by Sumerlin). A key characteristic of this system is that it relies on van der Waals interactions rather than the reformation of hydrogen or covalent bonds for repair. Science , this issue p. 220 ; see also p. 150 |
Databáze: | OpenAIRE |
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