The impact of the physical state and the reaction phase in the direct mechanocatalytic Suzuki–Miyaura coupling reaction

Autor:	Kwangho Yoo, Sven Fabig, Sven Grätz, Lars Borchardt
Rok vydání:	2023
Předmět:	Physical and Theoretical Chemistry
Zdroj:	Faraday Discussions. 241:206-216
ISSN:	1364-5498 1359-6640
Popis:	The direct mechanocatalytic Suzuki-Miyaura coupling reaction, utilizing palladium milling balls as active catalysts, was investigated regarding the physical state of the reagents and the reaction phase. The substitution patterns and functional groups of different aryl iodides were varied and different boronic acid derivates were utilized to achieve a wide range of substrate combinations. In the neat grinding experiments, liquid aryl iodides were more reactive than solid ones and a steric influence of the substituents, especially pronounced in
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6e911fe7f756aa3bca5f14dd12b85533 https://doi.org/10.1039/d2fd00100d Zobrazit plný text záznamu