Access to well-defined isolated Fe(ii) centers on silica and their use in oxidation

Autor:	Emile Kuntz, Charbel Roukoss, Steven G. Fiddy, Jean-Marie Basset, Nuria Rendón, Christophe Copéret, Aimery De Mallmann
Rok vydání:	2007
Předmět:	Chemistry Spectrum Analysis X-Rays Cyclohexene Silicon Dioxide Inorganic Chemistry chemistry.chemical_compound Catalytic oxidation Cyclohexenone Organic chemistry Ferrous Compounds Well-defined Oxidation-Reduction Fumed silica Cyclohexene oxide
Zdroj:	Dalton Transactions. :5546
ISSN:	1477-9234 1477-9226
DOI:	10.1039/b711015d
Popis:	Well-defined Fe(II) isolated sites are obtained by reaction of diaryl-N,N'-diazadiene bis(neosilyl) iron (1) with an aerosil silica, SiO(2-(700)). This system can be used as a precursor for the catalytic oxidation of cyclohexene into cyclohexene oxide, cyclohexenol and cyclohexenone in the presence of H(2)O(2).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6dd824b6bfc5e5a587dacc4e56c55645 https://doi.org/10.1039/b711015d Zobrazit plný text záznamu