Coexistence of Tellurium Cations and Anions in Phosphonium‐Based Ionic Liquids

Autor: Matthias A. Grasser, Tobias Pietsch, Jan Blasius, Oldamur Hollóczki, Eike Brunner, Thomas Doert, Michael Ruck
Rok vydání: 2021
Předmět:
Zdroj: Chemistry – A European Journal. 28
ISSN: 1521-3765
0947-6539
DOI: 10.1002/chem.202103770
Popis: Elemental tellurium readily dissolves in ionic liquids (ILs) based on tetraalkylphosphonium cations even at temperatures below 100 °C. In the case of ILs with acetate, decanoate, or dicyanamide anions, dark red to purple colored solutions form. A study combining NMR, UV-Vis and Raman spectroscopy revealed the formation of tellurium anions (Te
Databáze: OpenAIRE