Microstructural Design of Silicon Nitride with Improved Fracture Toughness: II, Effects of Yttria and Alumina Additives

Autor: Shirley B. Waters, Manuel E. Brito, Chun-Hway Hsueh, Ellen Y. Sun, Kevin P. Plucknett, Paul F. Becher, Kiyoshi Hirao, K. B. Alexander
Rok vydání: 2005
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Zdroj: ResearcherID
Scopus-Elsevier
ISSN: 1551-2916
0002-7820
DOI: 10.1111/j.1151-2916.1998.tb02703.x
Popis: Significant improvements in the fracture resistance of self-reinforced silicon nitride ceramics have been obtained by tailoring the chemistry of the intergranular amorphous phase. First, the overall microstructure of the material was controlled by incorporation of a fixed amount of elongated s-Si3N4 seeds into the starting powder to regulate the size and fraction of the large reinforcing grains. With controlled microstructures, the interfacial debond strength between the reinforcement and the intergranular glass was optimized by varying the yttria-to-alumina ratio in the sintering additives. It was found that the steady-state fracture toughness value of these silicon nitrides increased with the Y:Al ratio of the oxide additives. The increased toughness was accompanied by a steeply rising R-curve and extensive interfacial debonding between the elongated s-Si3N4 grains and the intergranular glassy phase. Microstructural analyses indicate that the different fracture behavior is related to the Al (and O) content in the s´-SiAlON growth layer formed on the elongated s-Si3N4 grains during densification. The results imply that the interfacial bond strength is a function of the extent of Al and Si bonding with N and O in the adjoining phases with an abrupt structural/chemical interface achieved by reducing the Al concentration in both the intergranular phase and the s´-SiAlON growth layer. Analytical modeling revealed that the residual thermal expansion mismatch stress is not a dominant influence on the interfacial fracture behavior when a distinct s´-SiAlON growth layer forms. It is concluded that the fracture resistance of self-reinforced silicon nitrides can be improved by optimizing the sintering additives employed.
Databáze: OpenAIRE
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