Crystal structure and Hirshfeld surface analysis of (E)-1-[2,2-dichloro-1-(4-nitrophenyl)ethenyl]-2-(4-fluorophenyl)diazene
| Autor: | Namiq Q. Shikhaliyev, Flavien A. A. Toze, Gulnar T. Suleymanova, Mehmet Akkurt, Zeliha Atioğlu, Khanim N. Bagirova |
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| Přispěvatelé: | Kapadokya Üniversitesi, Uygulamalı Bilimler Yüksekokulu, Havacılık Elektrik ve Elektroniği Bölümü, Atioğlu, Zeliha |
| Jazyk: | angličtina |
| Rok vydání: | 2019 |
| Předmět: |
crystal structure
Hydrogen bond Chemistry Stacking General Chemistry Crystal structure Dihedral angle Condensed Matter::Mesoscopic Systems and Quantum Hall Effect Condensed Matter Physics Ring (chemistry) hydrogen bonding Research Communications 4-fluorophenyl ring Crystal lcsh:Chemistry Crystallography lcsh:QD1-999 Nitro 4-fluorophenyl ring Hirshfeld surface analysis General Materials Science nitro-substituted benzene ring |
| Zdroj: | Acta Crystallographica Section E: Crystallographic Communications, Vol 75, Iss 2, Pp 237-241 (2019) Acta Crystallographica Section E: Crystallographic Communications |
| ISSN: | 2056-9890 |
| Popis: | The dihedral angle between the 4-fluorophenyl ring and the nitro-substituted benzene ring of the title compound is 63.29 (8)°. In the crystal, molecules are linked by C—H⋯O hydrogen bonds into chains parallel to the c axis. The crystal packing is further stabilized by C—Cl⋯π, C—F⋯π and N—O⋯π interactions In the title compound, C14H8Cl2FN3O2, the 4-fluorophenyl ring and the nitro-substituted benzene ring form a dihedral angle of 63.29 (8)°. In the crystal, molecules are linked by C—H⋯O hydrogen bonds into chains running parallel to the c axis. The crystal packing is further stabilized by C—Cl⋯π, C—F⋯π and N—O⋯π interactions. The Hirshfeld surface analysis of the crystal structure indicates that the most important contributions to the crystal packing are from H⋯O/O⋯H (15.5%), H⋯H (15.3%), Cl⋯H/H⋯Cl (13.8%), C⋯H/H⋯C (9.5%) and F⋯H/H⋯F (8.2%) interactions. |
| Databáze: | OpenAIRE |
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