Volatile organic compounds in paper—an approach for identification of markers in aged books

Autor:	Elvira M.S.M. Gaspar, José C. Santana, Marcos B. Diniz, João F. Lopes
Rok vydání:	2010
Předmět:	Chromatography Chemistry Pulp (paper) engineering.material Mass spectrometry Biochemistry Analytical Chemistry chemistry.chemical_compound engineering Organic chemistry Gas chromatography Cellulose Enantiomer Chemical decomposition
Zdroj:	Analytical and Bioanalytical Chemistry. 397:369-380
ISSN:	1618-2650 1618-2642
DOI:	10.1007/s00216-010-3520-3
Popis:	Volatile organic compounds emitted from historical books made from cotton/linen rag and wood pulp paper have been studied. Different profiles were obtained using different solid-phase microextraction (SPME) fibres to access the compounds involved in the decomposition reactions occurring in cotton/linen rag and wood pulp paper upon natural ageing and precocious/accelerated degradation. Contact headspace solid-phase extraction coupled with gas chromatography/time-of-flight mass spectrometry (GC-TOF-MS) was improved as a non-destructive methodology for the analysis of historical books. Potential markers of cellulose degradation-linear hydrocarbons, linear aldehydes, and 2-furfural-together with potential markers of cotton/linen rag paper (isopropylic esters) were identified. Chiral analysis (SPME-c-GC-TOF-MS) showed that only the enantiomer (S)-2-ethyl-1-hexanol is present as an emanation compound in both types of paper. Validation studies for a larger number of books are being done.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6cfb82b5d683198ea19bdac167f73312 https://doi.org/10.1007/s00216-010-3520-3 Zobrazit plný text záznamu Plný text ve formátu PDF