Enhanced Gating Performance of Single-Molecule Conductance by Heterocyclic Molecules
| Autor: | Ya-Hao Wang, Shan Jin, Dong-Fang Li, Feng Yan, Yan-Feng Xi, Jing-Zhe Chen, Rui Cao, Yong Shao, Xiao-Shun Zhou, Ju-Fang Zheng |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
Materials science
Transistor Conductance Hardware_PERFORMANCEANDRELIABILITY 02 engineering and technology Gating equipment and supplies 010402 general chemistry 021001 nanoscience & nanotechnology Electrochemistry 01 natural sciences 0104 chemical sciences law.invention law Hardware_INTEGRATEDCIRCUITS Biophysics Molecule General Materials Science Physical and Theoretical Chemistry 0210 nano-technology Hardware_LOGICDESIGN |
| Zdroj: | The journal of physical chemistry letters. 12(2) |
| ISSN: | 1948-7185 |
| Popis: | Enhancing the gating performance of single-molecule conductance is significant for realizing molecular transistors. Herein, we report a new strategy to improve the electrochemical gating efficiency of single-molecule conductance with fused molecular structures consisting of heterocyclic rings of furan, thiophene, or selenophene. One order magnitude of gating ratio is achieved within a potential window of 1.2 V for the selenophene-based molecule, which is significantly greater than that of other heterocyclic and benzene ring molecules. This is caused by the different electronic structures of heterocyclic molecules and transmission coefficients |
| Databáze: | OpenAIRE |
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