A 3-D porous NiII coordination polymer constructed from oxalate and hydrazine linkers

Autor:	Fu-Ping Huang, Jun-Rong Meng, Han-Fu Liu, Peng-Fei Yao, He-Dong Bian, Jun-Bo Huang, Hai-Ye Li, Jie Tang
Rok vydání:	2020
Předmět:	Chemistry Coordination polymer Hydrazine 010402 general chemistry 010403 inorganic & nuclear chemistry 01 natural sciences Hydrothermal circulation Oxalate 0104 chemical sciences chemistry.chemical_compound Polymer chemistry Materials Chemistry Physical and Theoretical Chemistry Porosity
Zdroj:	Journal of Coordination Chemistry. 73:1097-1105
ISSN:	1029-0389 0095-8972
DOI:	10.1080/00958972.2020.1764546
Popis:	A NiII-MOF, {[Ni(C2O4)(N2H4)]·2H2O}n (1), was constructed by oxalate and hydrazine under hydrothermal conditions at 130 °C. Single-crystal X-ray structural analysis indicates that 1 has a 3-D porous architecture with (103) topology based on two kinds of 1-D zigzag [Ni(C2O4)]n chains with the same structure but different extension directions in the ab plane separated by N2H4 linker. 1 reveals antiferromagnetic behavior and thermal stability below 283 °C.
Databáze:	OpenAIRE
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