Synthesis and Spectroscopic Study of Iron(III) and Copper(II) Chloride Complexes with 2-(3,3-Dimethyl-1,2,3,4-tetrahydroisoquinolylidene-1)-5,5-dimethyl-2,3,5,6-tetrahydroimidazo[2,1-a]isoquinoline-3-one (L). The Crystal Structure of L

Autor: Yu. V. Shklyaev, V. V. Davydov, M. A. Ryabov, V. S. Sergienko, Valentina I. Sokol, N. Yu. Merkur'eva, S. A. Pervushina
Rok vydání: 2003
Předmět:
Zdroj: Scopus-Elsevier
ISSN: 1070-3284
DOI: 10.1023/b:ruco.0000003439.10454.67
Popis: Complexes of Fe(III) and Cu(II) chlorides with 2-(3,3,-dimethyl-1,2,3,4-tetrahydroisoquinolylidene-1)-5,5-dimethyl-2,3,5,6-tetrahydroimidazo[2,1-a]isoquinoline-3-one (L) were synthesized and studied by IR and electronic absorption spectroscopy. X-ray diffraction analysis of compound L was carried out. The molecule of L was found to crystallize in the form of cis-isomer with the proton localized on the nitrogen atom of the dihydroisoquinoline fragment.
Databáze: OpenAIRE