Self-assembly of a 'double dynamic covalent' amphiphile featuring a glucose-responsive imine bond

Autor:	Yun-Bao Jiang, Xuan-Xuan Chen, Xin Wu, Philip A. Gale, Zhao Li, Miao Zhang
Jazyk:	angličtina
Rok vydání:	2016
Předmět:	Macromolecular Substances Stereochemistry Proton Magnetic Resonance Spectroscopy Imine 010402 general chemistry 01 natural sciences Glucose responsive Catalysis Surface-Active Agents chemistry.chemical_compound Oxazines Amphiphile Materials Chemistry Amines Fluorescent Dyes Aqueous solution 010405 organic chemistry Metals and Alloys Galactose Fructose General Chemistry Boronic Acids Combinatorial chemistry 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials Glucose binding Glucose Models Chemical chemistry Covalent bond Benzaldehydes Ceramics and Composites Imines Self-assembly
Popis:	Glucose binding via boronate ester linkages selectively triggers imine bond formation between 4-formylphenylboronic acid and octylamine, leading to the formation of vesicular aggregates in aqueous solutions. This "double dynamic covalent assembly" allows the facile selective sensing of glucose against the otherwise serious interferant fructose, without the need to resort to synthetic effort.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6c813d685c44ada4e6da2059890dfe1d https://eprints.soton.ac.uk/393206/ Zobrazit plný text záznamu