Preorganized AgI Bimetallic Precursor with Labile Diphosphorus Ligands for a Programmed Synthesis of Organometallic–Organic Hybrid Polymers
| Autor: | Manfred Zabel, Mehdi Elsayed Moussa, Gábor Balázs, Michael Seidl, Alexander V. Virovets, Andrea Schreiner, Bianca Attenberger, Manfred Scheer |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2017 |
| Předmět: |
Diphosphorus
Dimer Supramolecular chemistry Molecular precursor 010402 general chemistry Photochemistry 01 natural sciences Catalysis chemistry.chemical_compound Pyridine Polymer chemistry Bimetallic strip chemistry.chemical_classification 010405 organic chemistry diphosphorus complex Communication Organic Chemistry General Chemistry Polymer Coordination Polymers hybrid coordination polymers Communications 0104 chemical sciences preorganized precursor organometallic node chemistry controlled synthesis Stoichiometry |
| Zdroj: | Chemistry (Weinheim an Der Bergstrasse, Germany) |
| ISSN: | 1521-3765 0947-6539 |
| Popis: | An AgI dimer capped with labile organometallic diphosphorus ligands [Cp2Mo2(CO)4(η2‐P2)] (Cp=C5H5) acts as a highly pre‐organized molecular precursor to direct the construction of 1D or 2D, and 3D organometallic–organic hybrid coordination polymers upon reaction with ditopic pyridine‐based linkers. The formation of the supramolecular aggregates can be controlled by the stoichiometry of the organic molecules, and the mechanism is supported by DFT calculations. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|