Planar geometry of 4-substituted-2,2'-bipyridines synthesized by Sonogashira and Suzuki cross-coupling reactions

Autor:	Hien M. Nguyen, T. T. Luong Thi, L. Van Meervelt, N. Nguyen Bich
Rok vydání:	2015
Předmět:	Sonogashira coupling General Chemistry Condensed Matter Physics Photochemistry Planarity testing Coupling reaction NMR spectra database chemistry.chemical_compound Bipyridine Crystallography chemistry Ferrocene Pyridine Molecule General Materials Science
Zdroj:	Crystallography Reports. 60:1100-1105
ISSN:	1562-689X 1063-7745
DOI:	10.1134/s1063774515070160
Popis:	Two 4-substituted 2,2'-bipyridines, namely 4-(ferrocenylethynyl)-2,2'-bipyridine (I) and 4-ferro- cenyl-2,2'-bipyridine (II) have been synthesized and fully characterized via single-crystal X-ray diffraction and 1H and 13C NMR analyses. The π-conjugated system designed from 2,2'-bipyridine modified with the ferrocenylethynyl and ferrocenyl groups shows the desired planarity. In the crystal packing of I and II, the molecules arrange themselves in head-to-tail and head-to-head motifs, respectively, resulting in consecutive layers of ferrocene and pyridine moieties. ispartof: Crystallography Reports vol:60 issue:7 pages:1100-1105 status: published
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6c3ec9d19437be814692d564738490f8 https://doi.org/10.1134/s1063774515070160 Zobrazit plný text záznamu Plný text ve formátu PDF