Synthesis and thermal decomposition of a novel zirconium acetato-propionate cluster: [Zr12]
| Autor: | Stéphanie Morlens, Dominique Luneau, Zeming Yu, Philippe Odier, Jean-Louis Soubeyroux, Guillaume Pilet, Sarah Petit |
|---|---|
| Přispěvatelé: | Saint-Gobain Recherche (SGR), SAINT-GOBAIN, Northwest Institute for Nonferrous Metal Research (NIN), Laboratoire des Multimatériaux et Interfaces (LMI), Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Magnétisme et Supraconductivité (MagSup), Institut Néel (NEEL), Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Centre National de la Recherche Scientifique (CNRS)-Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Centre National de la Recherche Scientifique (CNRS)-Université Joseph Fourier - Grenoble 1 (UJF) |
| Jazyk: | angličtina |
| Rok vydání: | 2011 |
| Předmět: |
Inorganic chemistry
chemistry.chemical_element 02 engineering and technology 010402 general chemistry La2Zr2O7 01 natural sciences Metal chemistry.chemical_compound Zirconium cluster MOD Cluster (physics) Molecule General Materials Science Thermal analysis Zirconium Thermal decomposition General Chemistry [CHIM.MATE]Chemical Sciences/Material chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics Decomposition Chemical solution deposition 0104 chemical sciences chemistry visual_art visual_art.visual_art_medium Physical chemistry Propionates 0210 nano-technology Derivative (chemistry) |
| Zdroj: | Solid State Sciences Solid State Sciences, Elsevier, 2011, 13, pp.665-670. ⟨10.1016/j.solidstatesciences.2010.12.041⟩ |
| ISSN: | 1293-2558 |
| DOI: | 10.1016/j.solidstatesciences.2010.12.041⟩ |
| Popis: | International audience; This work reports a novel Zirconium acetato-propionate complex herein called [Zr12] obtained by reaction of zirconium acetylacetonate Zr(acac)4 with propionic acid. The molecular structure has been determined by X-ray diffraction on single crystals and proposed to be [Zr12(m3-O)16(CH3CH2CO2)12(CH3CO2)8(m2- CH3CH2CO2)4]. This cluster involves oxo/hydroxo bonds in the direct surrounding of the metallic center. The decomposition of [Zr12] has been studied by thermal analysis and compared to Zr(acac)4. Its temperature of decomposition is much lower than for acetylacetonate derivative. In consequence, the formation of ZrO2 is easier from [Zr12] than from Zr(acac)4. This phenomenon highlights the influence of the molecular structure on the process of decomposition. The local surrounding of Zr in [Zr12] and in ZrO2 are very close, while it is markedly different in Zr(acac)4.This difference of environment of the metallic ions is at the origin of the huge difference of thermal behavior of both compounds. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect