Preparation of 2-Magnesiated 1,3,5-Triazines via an Iodine−Magnesium Exchange

Autor:	Zhihua Peng, Benjamin A. Haag, Paul Knochel
Rok vydání:	2010
Předmět:	Transmetalation chemistry Magnesium Organic Chemistry chemistry.chemical_element Organic chemistry Mg/exchange Physical and Theoretical Chemistry Iodine Biochemistry
Zdroj:	Organic Letters. 12:5398-5401
ISSN:	1523-7052 1523-7060
DOI:	10.1021/ol102173z
Popis:	Functionalized iodo- and diiodo-1,3,5-triazine derivatives readily undergo an I/Mg exchange with BuMgCl, sBuMgCl, or OctMgBr at low temperatures furnishing 2-magnesiated and 2-zincated 1,3,5-triazines (after transmetalation with ZnCl(2)). This method also offers a convenient access to dimagnesiated triazines. Furthermore, it allows the preparation of functionalized 1,3,5-triazinyl dimers and trimers, interesting for their opto-electronic properties.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6bed3dc58431ebda4e775ff89bae64a2 https://doi.org/10.1021/ol102173z Zobrazit plný text záznamu