Huge dielectric constants of the ferroelectric smectic-A phase in bent-shaped dimeric molecules

Autor: Masato Sone, Hiroki Ishizaki, Sungmin Kang, Shigemasa Nakasugi, Junji Watanabe
Rok vydání: 2021
Předmět:
Zdroj: Materials Advances. 2:7017-7023
ISSN: 2633-5409
DOI: 10.1039/d1ma00015b
Popis: We present the dielectric relaxation properties of the ferroelectric smectic-A (SmAPF) phase formed by a mixture of bent-shaped dimeric molecules α,ω-bis(4-alkoxyanilinebenzylidene-4′-carbonyloxy)pentanes with different alkyl chain lengths. The SmAPF phase shows a Goldstone-like mode at approximately 500 Hz, which can be attributed to the ferroelectricity and huge dielectric strength (Δe). Δe varies dramatically with the cell thickness; in particular, it attains more than 7000 in a 50 μm-thick cell, which is much higher compared to that reported in the bent-shaped molecules.
Databáze: OpenAIRE