Fluoride, bifluoride and trifluoromethyl complexes of iridium(i ) and rhodium(i )
| Autor: | Steven P. Nolan, Alexandra M. Z. Slawin, David B. Cordes, Fady Nahra, Byron J. Truscott |
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| Přispěvatelé: | European Research Council, EPSRC, University of St Andrews. School of Chemistry, University of St Andrews. EaSTCHEM |
| Rok vydání: | 2015 |
| Předmět: |
Trifluoromethyl
Chemistry Inorganic chemistry Metals and Alloys chemistry.chemical_element DAS General Chemistry Crystal structure QD Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Rhodium chemistry.chemical_compound Bifluoride Polymer chemistry Materials Chemistry Ceramics and Composites QD Reactivity (chemistry) Iridium Fluoride |
| Zdroj: | Chemical Communications. 51:62-65 |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/c4cc07772e |
| Popis: | The ERC (Advanced Researcher Award FUNCAT to SPN), the EPSRC and Sasol (Stipend to BJT) are gratefully acknowledged for support. Herein we report robust methods for the preparation and full characterisation of a range of Ir(I) and Rh(I) fluoride and bifluoride complexes using N-heterocyclic carbenes (NHCs) as ancillary ligands. The processes that link the fluoride and the bifluoride species are investigated and reports of the first Ir–bifluoride and Ir(I)–NHC and Rh(I)–NHC trifluoromethyl complexes are revealed. Postprint |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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