Investigation of low-cost oligoanthraquinones for alkaline, aqueous rechargeable batteries with cell potential up to 1.13 V
| Autor: | Anders Bentien, Kristina Wedege, Emil Dražević, Anders Søndergaard Andersen, Martin Lahn Henriksen, Mogens Hinge |
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| Rok vydání: | 2018 |
| Předmět: |
Materials science
Renewable Energy Sustainability and the Environment Supporting electrolyte Energy Engineering and Power Technology chemistry.chemical_element 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Electrochemistry 01 natural sciences Cathode Energy storage 0104 chemical sciences law.invention Anode chemistry.chemical_compound Nickel chemistry Chemical engineering law Surface modification Hydroxide Electrical and Electronic Engineering Physical and Theoretical Chemistry 0210 nano-technology |
| Zdroj: | Dražević, E, Andersen, A S, Wedege, K, Henriksen, M, Hinge, M & Bentien, A 2018, ' Investigation of low-cost oligoanthraquinones for alkaline, aqueous rechargeable batteries with cell potential up to 1.13 V ', Journal of Power Sources, vol. 381, pp. 94-100 . https://doi.org/10.1016/j.jpowsour.2018.01.092 |
| ISSN: | 0378-7753 |
| Popis: | The transition to renewable energy sources has created need for stationary, low-cost electrical energy storage. A possible technology to address both cost and environmental concerns are batteries based on organic materials. The use of oligoanthraquinones as a replacement for metal hydrides or cadmium in nickel hydroxide rechargeable batteries is investigated in detail regarding polymer composition, electrochemical reversibility and electroactive species cost. Two different oligoanthraquinones are paired with a nickel hydroxide cathode and demonstrate cycling stability dependent on parameters such as supporting electrolyte strength, C-rate, and anode swelling. The energy efficiencies are up to 75 % and the cell potential up to 1.13 V. Simple functionalization of the basic structure increases the cell potential by 100 mV. |
| Databáze: | OpenAIRE |
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