Synthesis, characterization and phytotoxic activity of hydroxylated isobenzofuran-1(3H)-ones
| Autor: | Julimar Luiz Pereira, Giuseppe Forlani, Drielly A. Paixão, Silvana Guilardi, Javier Ellena, Cleber P. A. Anconi, S.F. Da Silva, Róbson Ricardo Teixeira, W.B. De Almeida |
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| Rok vydání: | 2014 |
| Předmět: |
Photosynthetic electron transport chain
Isobenzofuran Isobenzofuran-1(3H)-ones Stereochemistry Chemical shift Organic Chemistry DFT calculations Analytical Chemistry Inorganic Chemistry chemistry.chemical_compound chemistry Phthalides X-ray analysis Phytotoxicity Radicle COMPOSTOS AROMÁTICOS X ray analysis Spectroscopy |
| Zdroj: | Repositório Institucional da USP (Biblioteca Digital da Produção Intelectual) Universidade de São Paulo (USP) instacron:USP |
| Popis: | Two hydroxylated isobenzofuranones 3 and 4 were synthesized from benzoic acids. The compounds were fully characterized by IR, NMR ( 1 H and 13 C), HRMS, and X-ray crystallography. Compounds 3 and 4 crystallized in the space group Pc and P2 1 /n, respectively. DFT calculations were used to confirm undoubtedly their NMR chemical shifts. Biological assays showed that these compounds are capable of interfering with the radicle growth of monocotyledonous and dicotyledonous species, whereas the photosynthetic electron transport chain was substantially unaffected. |
| Databáze: | OpenAIRE |
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