Galvanic replacement reaction as a route to prepare nanoporous aluminum for UV plasmonics
Autor: | Roman Krahne, Hai-Jun Jin, Maria Pachetti, Paolo Ponzellini, Denis Garoli, Sandro Cattarin, Andrea Schirato, Eugenio Calandrini, Remo Proietti Zaccaria, Giorgia Giovannini, Wei Yang, Francesco D'Amico, Alessandro Alabastri |
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Přispěvatelé: | Garoli, D., Schirato, A., Giovannini, G., Cattarin, S., Ponzellini, P., Calandrini, E., Zaccaria, R. P., D'Amico, F., Pachetti, M., Yang, W., Jin, H. -J., Krahne, R., Alabastri, A. |
Jazyk: | angličtina |
Rok vydání: | 2020 |
Předmět: |
metal enhanced fluorescence
Materials science Metal enhanced fluorescence General Chemical Engineering Alloy chemistry.chemical_element Physics::Optics Nanotechnology engineering.material medicine.disease_cause Article lcsh:Chemistry Metal symbols.namesake Aluminium ultraviolet medicine Physics::Atomic and Molecular Clusters General Materials Science Aluminum Nanoporous Plasmonic SERS Ultraviolet Plasmon plasmonic Nanoporou nanoporous lcsh:QD1-999 chemistry Surface-area-to-volume ratio visual_art aluminum visual_art.visual_art_medium symbols engineering Raman spectroscopy |
Zdroj: | Nanomaterials (Basel) 10 (2020). doi:10.3390/nano10010102 info:cnr-pdr/source/autori:Garoli D.; Schirato A.; Giovannini G.; Cattarin S.; Ponzellini P.; Calandrini E.; Zaccaria R.P.; D'amico F.; Pachetti M.; Yang W.; Jin H.-J.; Krahne R.; Alabastri A./titolo:Galvanic replacement reaction as a route to prepare nanoporous aluminum for UV plasmonics/doi:10.3390%2Fnano10010102/rivista:Nanomaterials (Basel)/anno:2020/pagina_da:/pagina_a:/intervallo_pagine:/volume:10 Nanomaterials Volume 10 Issue 1 Nanomaterials, Vol 10, Iss 1, p 102 (2020) |
Popis: | There is a growing interest in extending plasmonics applications into the ultraviolet region of the electromagnetic spectrum. Noble metals are commonly used in plasmonic, but their intrinsic optical properties limit their use above 350 nm. Aluminum is probably the most suitable material for UV plasmonics, and in this work we fabricated substrates of nanoporous aluminum starting from an alloy of Al2Mg3. The porous metal is obtained by means of a galvanic replacement reaction. Such nanoporous metal can be exploited to achieve a plasmonic material suitable for enhanced UV Raman spectroscopy and fluorescence. Thanks to the large surface to volume ratio, this material represents a powerful platform for promoting interaction between plasmonic substrates and molecules in the UV. |
Databáze: | OpenAIRE |
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