Metal Nanoparticles Confined within an Inorganic–Organic Framework Enable Superior Substrate-Selective Catalysis

Autor: Ningdong Feng, Huaming Li, Gang Chen, Yingguan Xiao, Shunsheng Cao, Jingjie Wu, Zhengliang Yin, Hui Xu, Hongping Li
Rok vydání: 2020
Předmět:
Zdroj: ACS Applied Materials & Interfaces. 12:42739-42748
ISSN: 1944-8252
1944-8244
DOI: 10.1021/acsami.0c10814
Popis: The search for catalysts with a perfect substrate selectivity toward the hydrogenation of nitroarenes is a goal of high importance, which still remains a significant challenge. Here, we designed a new type of catalyst with superior substrate selectivity by combining a space-confined effect and a hydrogen-bonding network, in which metal nanoparticles (MNPs) were confined in hierarchical hollow silica (HHS) with a poly(
Databáze: OpenAIRE