Desymmetrization of Achiral Heterobicyclic Alkenes through Catalytic Asymmetric Hydrophosphination

Autor:	Sumod A. Pullarkat, Yew Jin Ong, Tadayuki Kojima, Yongxin Li, Abdul Sadeer, Ce Qing Foo, Pak-Hing Leung
Rok vydání:	2018
Předmět:	010405 organic chemistry Chemistry Asymmetric carbon Organic Chemistry Hydrophosphination Organic chemistry General Chemistry 010402 general chemistry 01 natural sciences Biochemistry Desymmetrization 0104 chemical sciences Catalysis
Zdroj:	Chemistry, an Asian journal. 13(19)
ISSN:	1861-471X
Popis:	Asymmetric addition of diarylphosphines to oxa- and azabicyclic alkenes proceeded in the presence of a chiral phosphapalladacycle catalyst and a mild acid at room temperature to give exclusively the enantioenriched addition products in excellent yields and good selectivities. Three new chiral carbon centers were generated stereoselectively by the catalytic hydrophosphination reaction.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6af21f85eed724468bc4fd14cf3d58b6 https://pubmed.ncbi.nlm.nih.gov/30022614 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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