Excited state polarizabilities of conjugated molecules calculated using time dependent density functional theory
| Autor: | Laurens D. A. Siebbeles, R. Telesca, J.G. Snijders, Ferdinand C. Grozema, Harry T. Jonkman |
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| Přispěvatelé: | Molecular Energy Materials, Surfaces and Thin Films, Theoretical Chemistry |
| Rok vydání: | 2001 |
| Předmět: |
ELECTROABSORPTION SPECTROSCOPY
Stark effect triplet state General Physics and Astronomy symbols.namesake Polarizability Physics::Atomic and Molecular Clusters CHAINS Physics::Atomic Physics Singlet state EXCHANGE-ENERGY Physics::Chemical Physics Physical and Theoretical Chemistry Triplet state excited states density functional theory PHOTOSYNTHETIC PURPLE BACTERIA LIGHT-HARVESTING ANTENNAS Chemistry Time-dependent density functional theory electrostatics RESPONSE THEORY STARK SPECTROSCOPY Excited state symbols Density functional theory POLYMERS Atomic physics Ground state POLYENES APPROXIMATION |
| Zdroj: | Journal of Chemical Physics, 115(21), 10014-10021. AMER INST PHYSICS Journal of Chemical Physics, 115 (21), 2001 |
| ISSN: | 1089-7690 0021-9606 |
| DOI: | 10.1063/1.1415085 |
| Popis: | In this paper, time-dependent density functional theory (TDDFT) calculations of excited state polarizabilities of conjugated molecules are presented. The increase in polarizability upon excitation was obtained by evaluating the dependence of the excitation energy on an applied static electric field. The excitation energy was found to vary quadratically with the field strength. The excess polarizabilities obtained for singlet excited states are in reasonable agreement with the experimental results for the shorter oligomers, particularly if the experimental uncertainties are considered. For longer oligomers the excess polarizability is considerably overestimated, similar to DFT calculations of ground state polarizabilities. Excess polarizabilities of triplet states were found to be smaller than those for the corresponding singlet state, which agrees with experimental results that are available for triplet polarizabilities. Negative polarizabilities are obtained for the lowest singlet Ag states of longer oligomers. The polarizability of the lowest Bu and Ag excited states of the conjugated molecules studied here are determined mainly by the interaction between these two states. Upon application of a static electric field a quadratic Stark effect is observed in which the lower Bu state has a positive excess polarizability and the upper Ag state exhibits a decrease in polarizability upon excitation. All results are explained in terms of a sum-over-states description for the polarizability. |
| Databáze: | OpenAIRE |
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