Metal Sulfides@Carbon Microfiber Networks for Boosting Lithium Ion/Sodium Ion Storage via a General Metal–Aspergillus niger Bioleaching Strategy
| Autor: | Chunxiao Lv, Junzhi Li, La Li, Lili Wang, I. V. Zatovsky, Wei Han |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
Materials science
Sulfide chemistry.chemical_element Nanoparticle 02 engineering and technology Lithium Sulfides 010402 general chemistry 01 natural sciences Ion Metal Electric Power Supplies Carbon Fiber Bioleaching General Materials Science Electrodes Ions chemistry.chemical_classification Sodium Electric Conductivity 021001 nanoscience & nanotechnology 0104 chemical sciences chemistry Chemical engineering Metals visual_art Electrode visual_art.visual_art_medium Nanoparticles Aspergillus niger 0210 nano-technology Carbon |
| Zdroj: | ACS Applied Materials & Interfaces. 11:8072-8080 |
| ISSN: | 1944-8252 1944-8244 |
| DOI: | 10.1021/acsami.8b21976 |
| Popis: | The fabrication and design of electrodes that transfer more energy at high rates is very crucial for battery technology because of the increasing need for electrical energy storage. Usually, reducing a material’s volume expansion and improving its electrical conductivity can promote electron and Li+/Na+ ion transfer in nanostructured electrodes and improve rate capability and stability. Here, we demonstrate a general metal–Aspergillus niger bioleaching approach for preparing novel fungus-inspired electrode materials that may enable high-performance lithium ion/sodium ion batteries with one-dimensional architectures. The fungus functions as a natural template to provide large amounts of nitrogen/carbon sources, which are functionalized with metal sulfide nanoparticles, yielding various metal sulfide nanoparticles/nitrogen-doped carbonaceous fibers (MS/NCF (MS = ZnS, Co9S8, FeS, Cu1.81S)) with high conductivity. In addition, the as-obtained MS/NCF has a uniform fiber architecture and abundant porous structu... |
| Databáze: | OpenAIRE |
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