Vibrations of a single adsorbed organic molecule: anharmonicity matters!
| Autor: | Yohann Scribano, David M. Benoit, Norbert Maurer, Anna Tschetschetkin, Paul J. Ziemann, Inga S. Ulusoy, B. Koslowski |
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| Rok vydání: | 2010 |
| Předmět: |
Chemistry
Anharmonicity General Physics and Astronomy Infrared spectroscopy Self-assembled monolayer Electronic structure Spectral line symbols.namesake Computational chemistry Chemical physics symbols Molecule Physics::Chemical Physics Physical and Theoretical Chemistry Raman spectroscopy Quantum tunnelling |
| Zdroj: | Physical chemistry chemical physics : PCCP. 13(2) |
| ISSN: | 1463-9084 |
| Popis: | Vibrational spectroscopy is a powerful tool to identify molecules and to characterise their chemical state. Inelastic electron tunnelling spectroscopy (IETS) combined with scanning tunnelling microscopy (STM) allows the application of vibrational analysis to a single molecule. Up to now, IETS was restricted to small species due to the complexity of vibration spectra for larger molecules. We extend the horizon of IETS for both experiment and theory by measuring the STM-IETS spectra of mercaptopyridine adsorbed on the (111) surface of gold and comparing it to theoretical spectra. Such complex spectra with more than 20 lines can be reliably determined and computed leading to completely new insights. Experimentally, the vibrational spectra exhibit a dependence on the specific adsorption site of the molecules. Theoretically, this dependence is only accessible if anharmonic contributions to the interaction potentials are included. These joint experimental and theoretical advances open new perspectives for structure determination of organic adlayers. |
| Databáze: | OpenAIRE |
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