Electrochemical properties of a cobalt(II) complex with sulfadiazine and 1,3-bis(pyridin-4-yl)propane

Autor:	Jian-Guo Pan, Zhao Yayun, Zhao Xiuhua, Xing Li, Jie Zhang
Rok vydání:	2013
Předmět:	Hydrogen bond Inorganic chemistry chemistry.chemical_element General Medicine Crystal structure Electrochemistry Medicinal chemistry Redox General Biochemistry Genetics and Molecular Biology chemistry.chemical_compound chemistry Propane Thermal stability Flack parameter Cobalt
Zdroj:	Acta Crystallographica Section C Crystal Structure Communications. 69:1096-1099
ISSN:	0108-2701
DOI:	10.1107/s010827011302297x
Popis:	catena-Poly[[bis{4-[(pyrimidin-2-ylazanidyl)sulfonyl]aniline}cobalt(II)]-bis[μ-1,3-bis(pyridin-4-yl)propane]], [Co(C10H8N4O4S2)2(C13H14N2)]nor [Co(L)2(bpp)]n, crystallizes as a one-dimensional polymeric structure which is further stabilized by intermolecular hydrogen bonding. The refined Flack parameter, −0.001 (10), indicates that the model represents the correct absolute structure. Investigation of the thermal stability shows that the complex is stable up to 543 K. The structure is of interest with respect to its electrochemical properties in the reduction reaction of H2O2to H2O.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::69d27e95fd5baef3cba4ba67b68c3e1a https://doi.org/10.1107/s010827011302297x Zobrazit plný text záznamu Plný text