Beta-chlorovinylsilanes as masked alkynes in oligoyne assembly: synthesis of the first aryl-end-capped dodecayne

Autor:	Simon M. E. Simpkins, Michael D. Weller, Liam R. Cox
Rok vydání:	2007
Předmět:	chemistry.chemical_compound Absorption spectroscopy Chemistry Aryl Materials Chemistry Metals and Alloys Ceramics and Composites Organic chemistry General Chemistry Mass spectrometry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials
Zdroj:	Chemical communications (Cambridge, England). (39)
ISSN:	1359-7345
Popis:	An aryl-end-capped dodecayne has been prepared using a four-fold fluoride-mediated dechlorosilylation of a masked dodecayne precursor containing four beta-chlorovinylsilane residues that serve as masked alkynes; the unstable dodecayne product has been characterised by UV-vis absorption spectroscopy and 'matrix-free' MALDI-TOF mass spectrometry.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::69b54b00f5369ee3eb2b3577499e1fe3 https://pubmed.ncbi.nlm.nih.gov/17912407 Zobrazit plný text záznamu