Coordination chemistry and photoswitching of dinuclear macrocyclic cadmium-, nickel-, and zinc complexes containing azobenzene carboxylato co-ligands
| Autor: | Tobias Severin, Daniel Fuhrmann, Jens Bergmann, Jennifer Klose, Bernd Abel, Berthold Kersting, Jan Griebel, Peter Hahn, Alexander Jeremies |
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| Jazyk: | angličtina |
| Rok vydání: | 2019 |
| Předmět: |
chemistry.chemical_classification
complexes Photoisomerization Chemistry Ligand cadmium Organic Chemistry zinc azobenzene carboxylates Crystal structure Nuclear magnetic resonance spectroscopy Full Research Paper Coordination complex lcsh:QD241-441 chemistry.chemical_compound Crystallography nickel Azobenzene lcsh:Organic chemistry lcsh:Q Carboxylate Isostructural lcsh:Science macrocyclic ligands |
| Zdroj: | Beilstein Journal of Organic Chemistry, Vol 15, Iss 1, Pp 840-851 (2019) Beilstein Journal of Organic Chemistry |
| ISSN: | 1860-5397 |
| Popis: | The synthesis of mixed-ligand complexes of the type [M2L(μ-L')]+, where L represents a 24-membered macrocyclic hexaaza-dithiophenolate ligand, L' is an azobenzene carboxylate co-ligand, and M = Cd(II), Ni(II) or Zn(II), is reported. A series of new complexes were synthesized, namely [M2L(μ-L')]+ (L' = azo-H, M = Cd (1), Ni (2); L' = azo-OH, M = Zn (3), Ni (4); L' = azo-NMe2, M = Zn (5), Cd (6), Ni (7); L' = azo-CO2Me, M = Cd (8), Ni (9)), and characterized by elemental analysis, electrospray ionization mass spectrometry (ESIMS), IR, UV–vis and NMR spectroscopy (for diamagnetic Zn and Cd complexes) and X-ray single crystal structure analysis. The crystal structures of 3' and 5–8 display an isostructural series of compounds with bridging azobenzene carboxylates in the trans form. The paramagnetic Ni complexes 2, 4 and 7 reveal a weak ferromagnetic exchange interaction with magnetic exchange coupling constant values between 21 and 23 cm−1 (H = −2JS1S2). Irradiation of 1 with λ = 365 nm reveals a photoisomerization of the co-ligand from the trans to the cis form. |
| Databáze: | OpenAIRE |
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